Identification |
Product name: |
Phosphorus tribromide |
English name: |
phosphorus tribromide |
Molecular formula: |
PBr3 |
Molecular weight: |
270.72 |
Structural formula: |
 |
CAS No.: |
7789-60-8 |
RTECS No.: |
TH4460000 |
HS code: |
2903399090 |
UN No: |
UN 1808 8/PG 2 |
Dangerous goods code: |
C |
IMDG Code Page: |
|
Physical and Chemical Properties |
Appearance and properties: |
Colorless fuming liquid. There is a pungent smell. |
Uses: |
Organic synthesis is used as brominating agent. reducing agent. Used to analyze sugar and oxygen. |
Melting point: |
-40 °C |
Boiling point: |
175 °C(lit.) |
Relative density (water=1): |
2.88 g/mL at 20 °C(lit.) |
Moisture ≤: |
0.05% |
Phosphorus tribromideAssay ≥ |
99% |
PH value: |
6.0~8.0 |
Saturated vapor pressure (kPa): |
0.27 psi ( 54 °C) |
Solubility: |
Miscible with acetone, chloroform, carbon tetrachloride, carbon disulfide |
Critical temperature (℃): |
- |
Critical pressure (MPa): |
- |
Heat of combustion (kj/mol): |
- |
Combustion and explosion hazard |
Conditions to avoid: |
Humid air. |
Flammability: |
- |
Building regulation fire insurance classification: |
- |
Flash point (℃): |
172.9°C |
Self-Ignition temperature(℃): |
- |
Lower explosive limit (V%): |
- |
Upper explosive limit (V%): |
- |
Hazardous characteristics: |
Reacts with water or acid to generate heat or even explode |
Combustion (decomposition) products: |
Hydrogen bromide, phosphorus oxide, phosphorane |
Stability: |
Stable |
Incompatible materials: |
Strong alkalis, water, alcohols, strong oxidants, acids, alkalis, potassium, sodium |
Polymerization hazards: |
Not appearing |
Fire fighting methods: |
Dry sand, carbon dioxide. Water is forbidden. |
Risk category: |
8.1 |
Packaging sign of Dangerous goods: |
corrosion |
Packaging and transportation |
Packing group: |
III |
Directions for storage and transportation: |
The warehouse is ventilated, low-temperature and dry; stored separately from alkalis, oxidants, organic matter, and flammable materials |